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  • MagLab scientists discover thermoelectric properties in promising class of materials

    Exploring an area overlooked by other scientists, physicists at the Florida State University-

    headquartered  National High  Magnetic  Field Laboratory have discovered that a class of 

    materials  called  "1-2-20s" have  very  promising  thermoelectric  properties, opening the 

    floodgates for further research into these fascinating materials.

    The study was published in Science Advances.


    Thermoelectric devices can produce electricity if there is a temperature difference between 

    the two ends. They can also do the opposite: use electricity to absorb or release heat. This 

    property has many potential applications, from compressor-free refrigeration to power 

    generation in space to recouping all the energy wasted by car engines (about 40 percent) that 

    escapes through heat.


    "It's not free energy," said MagLab physicist Ryan Baumbach, corresponding author on the 

    paper, "but it's the next best thing."


    Most materials have very little thermoelectric effect. That's because the transfer of electricity 

    across a material and the transfer of heat usually go hand in hand. In general, nature wants to 

    keep heat and electrical conductivity linked, but to have good thermoelectric performance, 

    these two properties need to be decoupled.


    About  two  years  ago,  Baumbach  suggested  that  Kaya  Wei,  the  MagLab's Jack Crow 

    postdoctoral fellow and a member of Baumbach's research group, study a "1-2-20" material 

    that seemed like a good candidate for thermoelectricity.


    The specific material Baumbach proposed featured three basic ingredients in a "1-2-20" ratio: 

    the element ytterbium; a transition metal (either cobalt, rhodium or iridium); and the element 

    zinc. Baumbach had a hunch this compound had what it takes, if manipulated properly in his 

    lab, to thumb its nose at nature and unlink thermal conductivity from heat conductivity.


    Using high-temperature furnaces in Baumbach's lab, Wei synthesized the compound in crystal 

    form and subjected the samples to a gauntlet of measurements. The results confirmed that, at 

    low temperatures, the material was in fact a promising thermoelectric material.

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